| R32 | 25 |  Juan Carlos FerreroClay | 94 |  Potito StaraceClay | 7-6(3) 4-6 6-3 | 3 | 168 | 1 | 1 | 78.7% | 64.6% | 46.2% | 14/17 |
| R32 | 118 |  Lukas DlouhyClay | 68 | Alessio Di MauroClay | 6-3 6-2 | 3 | 61 | 3 | 2 | 66.0% | 75.8% | 58.8% | 1/2 |
| R32 | 153 |  Juan-Pablo GuzmanClay | 124 |  Kevin KimClay | 6-4 6-2 | 3 | 61 | 7 | 1 | 69.4% | 72.1% | 42.1% | 3/4 |
| R32 | 36 | Gaston GaudioClay | 46 |  Luis HornaClay | 1-1 RET | 3 | 15 | 2 | 0 | 75.0% | 100.0% | 100.0% | 0/0 |
| R32 | 28 | Nicolas AlmagroClay | 158 | Mariano ZabaletaClay | 6-3 6-4 | 3 | 81 | 14 | 0 | 62.7% | 81.0% | 36.0% | 5/6 |
| R32 | 59 | Ruben Ramirez HidalgoClay | 234 |  Santiago GonzalezClay | 6-4 6-3 | 3 | 76 | 1 | 6 | 57.4% | 66.7% | 55.2% | 3/6 |
| R32 | 93 | Diego HartfieldClay | 224 | Hugo ArmandoClay | 6-4 7-6(4) | 3 | 116 | 1 | 1 | 76.5% | 78.8% | 50.0% | 4/5 |
| R32 | 47 | Carlos MoyaClay | 216 | Bruno EchagarayClay | 6-3 6-4 | 3 | 69 | 8 | 1 | 61.5% | 81.3% | 65.0% | 2/3 |
| R32 | 53 |  Nicolas MassuClay | 58 | Juan MonacoClay | 7-6(4) 7-5 | 3 | 123 | 8 | 4 | 63.5% | 74.5% | 70.4% | 0/1 |
| R32 | 109 | Stefano GalvaniClay | 74 | Jan HajekClay | 6-3 6-2 | 3 | 61 | 10 | 2 | 53.3% | 87.5% | 50.0% | 1/1 |
| R32 | 90 |  Nicolas DevilderClay | 197 | Fabio FogniniClay | 7-6(2) 6-7(5) 6-4 | 3 | 183 | 2 | 4 | 78.7% | 68.0% | 55.6% | 6/8 |
| R32 | 35 | Juan Ignacio ChelaClay | 72 | Sergio RoitmanClay | 6-3 6-2 | 3 | 74 | 3 | 1 | 63.5% | 81.8% | 52.6% | 1/2 |
| R32 | 38 | Jose AcasusoClay | 66 | Albert MontanesClay | 6-0 7-5 | 3 | 73 | 10 | 0 | 75.0% | 81.8% | 81.8% | 0/0 |
| R32 | 116 | Jiri VanekClay | 62 | Martin Vassallo ArguelloClay | 2-6 6-1 6-3 | 3 | 111 | 5 | 3 | 72.0% | 63.0% | 47.6% | 1/5 |
| R32 | 105 | Oscar HernandezClay | 115 | Fernando VicenteClay | 6-2 7-5 | 3 | 95 | 0 | 1 | 81.8% | 82.2% | 50.0% | 1/1 |
| R32 | 29 | Agustin CalleriClay | 73 | Alberto MartinClay | 6-3 6-2 | 3 | 69 | 11 | 1 | 55.4% | 83.9% | 56.0% | 1/1 |
| R16 | 25 | Juan Carlos FerreroClay | 118 | Lukas DlouhyClay | 6-3 7-6(2) | 3 | 124 | 2 | 1 | 77.9% | 66.7% | 58.8% | 9/11 |
| R16 | 36 | Gaston GaudioClay | 153 | Juan-Pablo GuzmanClay | 1-6 6-3 6-2 | 3 | 120 | 1 | 3 | 70.1% | 65.6% | 38.5% | 4/8 |
| R16 | 28 | Nicolas AlmagroClay | 59 | Ruben Ramirez HidalgoClay | 6-1 4-6 7-6(2) | 3 | 113 | 10 | 9 | 55.6% | 82.2% | 44.4% | 4/8 |
| R16 | 47 | Carlos MoyaClay | 93 | Diego HartfieldClay | 4-6 6-1 6-4 | 3 | 113 | 10 | 9 | 55.6% | 82.2% | 44.4% | 4/8 |
| R16 | 53 | Nicolas MassuClay | 109 | Stefano GalvaniClay | 7-6(2) 6-3 | 3 | 121 | 3 | 4 | 58.7% | 65.9% | 61.3% | 5/7 |
| R16 | 35 | Juan Ignacio ChelaClay | 90 | Nicolas DevilderClay | 6-0 6-4 | 3 | 78 | 4 | 2 | 58.2% | 78.1% | 56.5% | 4/4 |
| R16 | 38 | Jose AcasusoClay | 116 | Jiri VanekClay | 6-1 6-2 | 3 | 70 | 2 | 1 | 52.4% | 86.4% | 65.0% | 3/3 |
| R16 | 29 | Agustin CalleriClay | 105 | Oscar HernandezClay | 4-6 6-3 6-3 | 3 | 119 | 11 | 0 | 61.3% | 79.6% | 64.5% | 5/6 |
| QF | 25 | Juan Carlos FerreroClay | 36 | Gaston GaudioClay | 6-4 6-1 | 3 | 86 | 2 | 0 | 71.8% | 71.4% | 90.9% | 2/3 |
| QF | 47 | Carlos MoyaClay | 28 | Nicolas AlmagroClay | 7-6(3) 6-3 | 3 | 95 | 11 | 0 | 69.7% | 71.7% | 47.8% | 6/7 |
| QF | 35 | Juan Ignacio ChelaClay | 53 | Nicolas MassuClay | 6-3 6-7(6) 7-5 | 3 | 219 | 2 | 3 | 65.1% | 76.1% | 47.4% | 5/9 |
| QF | 29 | Agustin CalleriClay | 38 | Jose AcasusoClay | 6-3 6-4 | 3 | 84 | 7 | 2 | 46.6% | 70.4% | 48.4% | 3/6 |
| SF | 47 | Carlos MoyaClay | 25 | Juan Carlos FerreroClay | 2-6 6-2 6-3 | 3 | 110 | 4 | 4 | 56.0% | 70.6% | 47.5% | 2/4 |
| SF | 35 | Juan Ignacio ChelaClay | 29 | Agustin CalleriClay | 4-6 5-5 RET | 3 | 95 | 0 | 3 | 67.7% | 76.2% | 40.0% | 2/4 |
| F | 35 | Juan Ignacio ChelaClay | 47 | Carlos MoyaClay | 6-3 7-6(2) | 3 | 106 | 2 | 3 | 67.5% | 74.1% | 57.7% | 3/3 |
