| R32 | 113 |  Alessio Di MauroClay | 7 |  Guillermo CoriaClay | 6-2 6-4 | 3 | 83 | 3 | 1 | 52.5% | 80.6% | 39.3% | 5/7 |
| R32 | 55 |  Boris PashanskiClay | 97 |  Ivo MinarClay | 2-6 6-3 7-5 | 3 | 108 | 11 | 4 | 66.2% | 73.5% | 64.0% | 3/5 |
| R32 | 101 |  Tomas BehrendClay | 106 | Jiri VanekClay | 7-6(4) 5-7 6-3 | 3 | 138 | 4 | 4 | 50.5% | 74.0% | 57.1% | 2/6 |
| R32 | 45 | Juan Ignacio ChelaClay | 71 | Juan MonacoClay | 4-6 7-6(4) 3-0 RET | 3 | 124 | 5 | 5 | 66.7% | 76.9% | 50.0% | 1/3 |
| R32 | 30 |  Carlos MoyaClay | 346 |  Miguel Gallardo-VallesClay | 3-6 6-4 7-5 | 3 | 105 | 12 | 5 | 67.6% | 74.0% | 42.9% | 5/8 |
| R32 | 96 | Albert MontanesClay | 146 | Juan Martin del PotroClay | 6-2 5-3 RET | 3 | 67 | 1 | 1 | 62.5% | 84.0% | 80.0% | 1/1 |
| R32 | 100 | Nicolas AlmagroClay | 95 | Fernando VicenteClay | 6-3 4-6 6-4 | 3 | 123 | 6 | 2 | 71.6% | 63.5% | 64.0% | 3/7 |
| R32 | 35 | Jose AcasusoClay | 186 | Santiago GonzalezClay | 6-2 6-1 | 3 | 62 | 0 | 1 | 48.7% | 73.7% | 75.0% | 0/0 |
| R32 | 103 |  Juan Antonio MarinClay | 37 |  Florent SerraClay | 6-4 6-7(4) 6-4 | 3 | 166 | 5 | 1 | 60.2% | 73.8% | 44.2% | 5/8 |
| R32 | 68 |  Luis HornaClay | 76 | Lukas DlouhyClay | 6-4 6-4 | 3 | 81 | 4 | 1 | 70.2% | 80.0% | 41.2% | 1/2 |
| R32 | 69 | Agustin CalleriClay | 91 |  Nicolas LapenttiClay | 6-3 6-3 | 3 | 86 | 6 | 2 | 46.0% | 87.0% | 59.3% | 4/5 |
| R32 | 58 | Alberto MartinClay | 32 | Filippo VolandriClay | 6-0 2-6 6-2 | 3 | 94 | 4 | 4 | 51.2% | 65.9% | 51.3% | 6/9 |
| R32 | 44 |  Nicolas MassuClay | 78 | Carlos BerlocqClay | 6-2 7-5 | 3 | 123 | 3 | 2 | 59.4% | 68.4% | 53.8% | 2/4 |
| R32 | 88 |  Marcos DanielClay | 122 |  Kevin KimClay | 7-5 6-3 | 3 | 80 | 4 | 1 | 74.1% | 62.5% | 64.3% | 1/3 |
| R32 | 115 |  Razvan SabauClay | 89 | Potito StaraceClay | 0-6 7-5 6-3 | 3 | 113 | 2 | 6 | 60.2% | 59.3% | 46.2% | 9/14 |
| R32 | 8 | Gaston GaudioClay | 110 | Albert PortasClay | 7-5 6-2 | 3 | 89 | 2 | 1 | 66.7% | 77.5% | 55.0% | 1/1 |
| R16 | 113 | Alessio Di MauroClay | 55 | Boris PashanskiClay | 1-6 6-3 6-4 | 3 | 119 | 14 | 0 | 60.0% | 71.1% | 40.0% | 2/6 |
| R16 | 45 | Juan Ignacio ChelaClay | 101 | Tomas BehrendClay | 6-1 2-6 6-2 | 3 | 112 | 7 | 2 | 58.4% | 75.0% | 43.2% | 11/13 |
| R16 | 96 | Albert MontanesClay | 30 | Carlos MoyaClay | 2-6 7-6(5) 6-4 | 3 | 139 | 7 | 2 | 66.4% | 68.0% | 39.5% | 10/13 |
| R16 | 100 | Nicolas AlmagroClay | 35 | Jose AcasusoClay | 6-3 RET | 3 | 36 | 2 | 0 | 56.5% | 84.6% | 90.0% | 0/0 |
| R16 | 68 | Luis HornaClay | 103 | Juan Antonio MarinClay | 6-3 7-6(4) | 3 | 131 | 13 | 1 | 67.1% | 70.9% | 55.6% | 6/8 |
| R16 | 69 | Agustin CalleriClay | 58 | Alberto MartinClay | 6-3 6-2 | 3 | 70 | 7 | 3 | 63.3% | 84.2% | 45.5% | 3/3 |
| R16 | 88 | Marcos DanielClay | 44 | Nicolas MassuClay | 6-4 6-4 | 3 | 98 | 5 | 0 | 78.6% | 72.7% | 25.0% | 0/2 |
| R16 | 8 | Gaston GaudioClay | 115 | Razvan SabauClay | 6-3 3-6 6-2 | 3 | 119 | 7 | 3 | 70.2% | 74.6% | 48.0% | 2/3 |
| QF | 45 | Juan Ignacio ChelaClay | 113 | Alessio Di MauroClay | 7-5 6-2 | 3 | 100 | 2 | 3 | 60.3% | 71.4% | 52.2% | 1/3 |
| QF | 100 | Nicolas AlmagroClay | 96 | Albert MontanesClay | 6-4 6-0 | 3 | 64 | 7 | 0 | 58.7% | 70.4% | 68.4% | 2/3 |
| QF | 68 | Luis HornaClay | 69 | Agustin CalleriClay | 6-3 6-4 | 3 | 82 | 3 | 1 | 69.8% | 78.4% | 68.8% | 0/0 |
| QF | 8 | Gaston GaudioClay | 88 | Marcos DanielClay | 6-4 2-6 6-3 | 3 | 134 | 3 | 8 | 61.7% | 70.7% | 41.7% | 8/12 |
| SF | 45 | Juan Ignacio ChelaClay | 100 | Nicolas AlmagroClay | 6-2 6-2 | 3 | 81 | 1 | 2 | 60.0% | 66.7% | 57.1% | 5/5 |
| SF | 68 | Luis HornaClay | 8 | Gaston GaudioClay | 4-6 6-4 6-3 | 3 | 156 | 9 | 1 | 67.3% | 75.0% | 42.4% | 8/10 |
| F | 68 | Luis HornaClay | 45 | Juan Ignacio ChelaClay | 7-6(5) 6-4 | 3 | 122 | 7 | 1 | 62.2% | 64.7% | 61.3% | 4/6 |
