| R32 | 6 |  Carlos MoyaClay | 143 |  Nicolas LapenttiClay | 6-4 7-6(4) | 3 | 98 | 5 | 3 | 78.5% | 82.4% | 50.0% | 1/2 |
| R32 | 74 |  Mariano PuertaClay | 84 | Guillermo Garcia-LopezClay | 6-3 7-6(3) | 3 | 98 | 10 | 1 | 80.3% | 71.4% | 66.7% | 2/3 |
| R32 | 97 | Felix MantillaClay | 225 |  Miguel Gallardo-VallesClay | 6-1 6-1 | 3 | 56 | 2 | 0 | 71.8% | 75.0% | 81.8% | 0/0 |
| R32 | 47 | David FerrerClay | 54 |  Ricardo MelloClay | 4-6 6-3 6-2 | 3 | 102 | 2 | 2 | 61.6% | 82.2% | 53.6% | 1/3 |
| R32 | 12 | Guillermo CanasClay | 103 | Edgardo MassaClay | 6-4 2-2 RET | 3 | 59 | 4 | 0 | 54.1% | 75.0% | 76.5% | 0/0 |
| R32 | 187 |  Nicolas DevilderClay | 58 | Jose AcasusoClay | 6-4 6-4 | 3 | 59 | 4 | 0 | 54.1% | 75.0% | 76.5% | 0/0 |
| R32 | 77 | Santiago VenturaClay | 87 | Nicolas AlmagroClay | 2-6 6-4 6-2 | 3 | 96 | 4 | 1 | 51.3% | 77.5% | 57.9% | 2/4 |
| R32 | 39 | Rafael NadalClay | 81 | Alex CalatravaClay | 6-4 6-4 | 3 | 83 | 5 | 1 | 64.3% | 77.8% | 55.0% | 1/2 |
| R32 | 27 |  Jiri NovakClay | 253 |  Juan Antonio MarinClay | 6-3 7-5 | 3 | 84 | 6 | 1 | 82.0% | 80.0% | 36.4% | 2/2 |
| R32 | 86 | Oscar HernandezClay | 93 | David SanchezClay | 6-4 6-2 | 3 | 76 | 1 | 4 | 64.0% | 81.3% | 55.6% | 2/3 |
| R32 | 59 | Agustin CalleriClay | 156 | Olivier PatienceClay | 7-5 7-6(5) | 3 | 101 | 12 | 3 | 56.8% | 76.2% | 59.4% | 2/4 |
| R32 | 90 | Juan MonacoClay | 23 | Juan Ignacio ChelaClay | 6-2 6-3 | 3 | 68 | 3 | 3 | 63.6% | 85.7% | 50.0% | 4/5 |
| R32 | 42 |  Filippo VolandriClay | 52 | Mariano ZabaletaClay | 6-2 7-6(6) | 3 | 82 | 2 | 1 | 57.1% | 72.2% | 59.3% | 2/4 |
| R32 | 56 | Alberto MartinClay | 91 | Jiri VanekClay | 6-0 2-6 7-6(1) | 3 | 114 | 4 | 2 | 58.3% | 69.4% | 57.1% | 2/4 |
| R32 | 95 | Albert MontanesClay | 240 | Alejandro HernandezClay | 6-2 6-3 | 3 | 72 | 2 | 1 | 72.5% | 75.9% | 90.9% | 0/0 |
| R32 | 80 | Tomas ZibClay | 8 | Gaston GaudioClay | 2-6 7-5 RET | 3 | 99 | 7 | 3 | 52.5% | 71.0% | 50.0% | 2/4 |
| R16 | 74 | Mariano PuertaClay | 6 | Carlos MoyaClay | 4-6 6-3 6-4 | 3 | 131 | 3 | 0 | 70.3% | 71.8% | 50.0% | 5/6 |
| R16 | 97 | Felix MantillaClay | 47 | David FerrerClay | 7-5 6-2 | 3 | 80 | 0 | 2 | 74.5% | 70.7% | 50.0% | 0/2 |
| R16 | 12 | Guillermo CanasClay | 187 | Nicolas DevilderClay | 6-0 7-5 | 3 | 92 | 3 | 2 | 57.4% | 74.2% | 60.9% | 2/3 |
| R16 | 39 | Rafael NadalClay | 77 | Santiago VenturaClay | 7-6(0) 6-2 | 3 | 104 | 3 | 1 | 68.3% | 76.7% | 65.0% | 4/5 |
| R16 | 27 | Jiri NovakClay | 86 | Oscar HernandezClay | 6-3 6-1 | 3 | 56 | 4 | 1 | 66.7% | 82.1% | 71.4% | 1/1 |
| R16 | 59 | Agustin CalleriClay | 90 | Juan MonacoClay | 7-6(4) 6-3 | 3 | 107 | 8 | 1 | 55.7% | 76.9% | 67.7% | 1/1 |
| R16 | 42 | Filippo VolandriClay | 56 | Alberto MartinClay | 7-6(5) 7-5 | 3 | 124 | 0 | 2 | 68.3% | 67.9% | 46.2% | 3/6 |
| R16 | 95 | Albert MontanesClay | 80 | Tomas ZibClay | 6-4 7-6(15) | 3 | 116 | 17 | 6 | 60.4% | 80.0% | 52.8% | 4/5 |
| QF | 74 | Mariano PuertaClay | 97 | Felix MantillaClay | 6-4 3-6 7-6(5) | 3 | 157 | 9 | 1 | 65.4% | 74.3% | 45.9% | 3/6 |
| QF | 39 | Rafael NadalClay | 12 | Guillermo CanasClay | 7-5 6-3 | 3 | 105 | 0 | 1 | 66.7% | 73.8% | 81.0% | 3/3 |
| QF | 59 | Agustin CalleriClay | 27 | Jiri NovakClay | 7-5 6-1 | 3 | 72 | 9 | 0 | 65.5% | 77.8% | 73.7% | 2/2 |
| QF | 95 | Albert MontanesClay | 42 | Filippo VolandriClay | 4-6 6-3 6-4 | 3 | 102 | 7 | 2 | 70.5% | 80.0% | 56.5% | 2/4 |
| SF | 39 | Rafael NadalClay | 74 | Mariano PuertaClay | 6-4 6-1 | 3 | 76 | 4 | 1 | 78.7% | 81.1% | 40.0% | 0/1 |
| SF | 95 | Albert MontanesClay | 59 | Agustin CalleriClay | 7-6(3) 1-6 7-6(4) | 3 | 149 | 6 | 0 | 64.3% | 65.3% | 47.5% | 5/10 |
| F | 39 | Rafael NadalClay | 95 | Albert MontanesClay | 6-1 6-0 | 3 | 52 | 5 | 2 | 77.8% | 85.7% | 50.0% | 0/0 |
