| R32 | 7 |  Carlos MoyaClay | 56 | David SanchezClay | 6-3 6-3 | 3 | 68 | 4 | 5 | 55.7% | 85.3% | 48.1% | 3/3 |
| R32 | 86 |  Richard GasquetClay | 113 |  Christophe RochusClay | 7-6(4) 3-6 6-3 | 3 | 119 | 10 | 7 | 57.0% | 73.6% | 45.0% | 5/9 |
| R32 | 92 |  Stefan KoubekClay | 98 |  Harel LevyClay | 3-6 7-5 6-4 | 3 | 118 | 6 | 3 | 62.9% | 78.6% | 36.4% | 4/9 |
| R32 | 44 |  Filippo VolandriClay | 80 | Galo BlancoClay | 7-5 4-6 7-5 | 3 | 159 | 1 | 4 | 74.6% | 63.6% | 60.0% | 7/11 |
| R32 | 63 |  Luis HornaClay | 21 |  Agustin CalleriClay | 7-6(5) 6-4 | 3 | 101 | 3 | 3 | 58.8% | 77.5% | 53.6% | 1/3 |
| R32 | 90 | Oscar HernandezClay | 106 | Dick NormanClay | 6-4 3-6 7-6(6) | 3 | 29 | 11 | 4 | 60.0% | 75.0% | 52.5% | 2/4 |
| R32 | 68 | David FerrerClay | 219 |  Miguel Gallardo-VallesClay | 6-2 7-6(4) | 3 | 87 | 4 | 1 | 75.0% | 68.8% | 75.0% | 4/6 |
| R32 | 39 | Juan Ignacio ChelaClay | 114 | Albert MontanesClay | 6-3 6-4 | 3 | 73 | 11 | 1 | 71.2% | 86.5% | 46.7% | 0/1 |
| R32 | 33 | Gaston GaudioClay | 78 | Jose AcasusoClay | 6-7(2) 7-6(1) 6-1 | 3 | 146 | 7 | 5 | 61.9% | 83.3% | 43.2% | 4/6 |
| R32 | 135 | Guillermo CanasClay | 133 | Marc LopezClay | 4-6 7-6(3) 7-5 | 3 | 201 | 6 | 7 | 60.6% | 76.2% | 48.8% | 4/7 |
| R32 | 82 | Ruben Ramirez HidalgoClay | 88 | Albert PortasClay | 6-3 7-6(4) | 3 | 92 | 6 | 6 | 59.5% | 80.9% | 40.6% | 6/8 |
| R32 | 36 | Mariano ZabaletaClay | 123 |  Giovanni LapenttiClay | 6-7(4) 6-2 6-3 | 3 | 123 | 10 | 5 | 57.6% | 71.4% | 80.6% | 4/5 |
| R32 | 38 | Felix MantillaClay | 121 | Olivier PatienceClay | 6-3 7-6(4) | 3 | 92 | 9 | 1 | 70.6% | 73.3% | 44.0% | 10/12 |
| R32 | 103 | Fernando VerdascoClay | 102 |  Tomas BehrendClay | 6-2 6-4 | 3 | 57 | 5 | 2 | 71.7% | 84.8% | 69.2% | 0/0 |
| R32 | 124 |  Jeff SalzensteinClay | 62 | Nicolas LapenttiClay | 6-1 3-6 6-1 | 3 | 94 | 7 | 1 | 72.7% | 78.6% | 52.4% | 7/8 |
| R32 | 13 |  Nicolas MassuClay | 281 | Alejandro HernandezClay | 6-2 6-0 | 3 | 64 | 4 | 1 | 50.0% | 80.0% | 65.0% | 0/0 |
| R16 | 7 | Carlos MoyaClay | 86 | Richard GasquetClay | 3-6 6-3 6-2 | 3 | 106 | 11 | 0 | 57.4% | 76.9% | 51.7% | 1/4 |
| R16 | 44 | Filippo VolandriClay | 92 | Stefan KoubekClay | 6-4 6-2 | 3 | 65 | 0 | 0 | 76.4% | 61.9% | 53.8% | 7/10 |
| R16 | 90 | Oscar HernandezClay | 63 | Luis HornaClay | 3-6 6-4 7-6(2) | 3 | 147 | 2 | 4 | 68.2% | 69.3% | 48.6% | 9/12 |
| R16 | 39 | Juan Ignacio ChelaClay | 68 | David FerrerClay | 6-3 6-3 | 3 | 83 | 4 | 2 | 68.4% | 64.1% | 55.6% | 3/5 |
| R16 | 135 | Guillermo CanasClay | 33 | Gaston GaudioClay | 6-4 6-3 | 3 | 107 | 2 | 4 | 48.1% | 71.1% | 46.3% | 8/11 |
| R16 | 82 | Ruben Ramirez HidalgoClay | 36 | Mariano ZabaletaClay | 7-5 6-3 | 3 | 97 | 5 | 6 | 59.2% | 64.4% | 54.8% | 6/8 |
| R16 | 103 | Fernando VerdascoClay | 38 | Felix MantillaClay | 4-6 6-4 6-0 | 3 | 91 | 6 | 3 | 53.7% | 83.3% | 58.1% | 0/2 |
| R16 | 13 | Nicolas MassuClay | 124 | Jeff SalzensteinClay | 6-1 6-3 | 3 | 66 | 6 | 1 | 65.8% | 88.0% | 84.6% | 1/1 |
| QF | 7 | Carlos MoyaClay | 44 | Filippo VolandriClay | 3-6 7-5 6-2 | 3 | 117 | 7 | 4 | 51.8% | 75.0% | 51.2% | 3/6 |
| QF | 39 | Juan Ignacio ChelaClay | 90 | Oscar HernandezClay | 3-6 6-0 6-2 | 3 | 102 | 3 | 2 | 66.2% | 83.7% | 36.4% | 5/7 |
| QF | 135 | Guillermo CanasClay | 82 | Ruben Ramirez HidalgoClay | 6-2 6-0 | 3 | 58 | 1 | 2 | 59.5% | 76.0% | 76.5% | 2/2 |
| QF | 103 | Fernando VerdascoClay | 13 | Nicolas MassuClay | 6-3 6-4 | 3 | 85 | 2 | 4 | 71.4% | 68.6% | 57.1% | 4/6 |
| SF | 7 | Carlos MoyaClay | 39 | Juan Ignacio ChelaClay | 6-2 7-6(4) | 3 | 97 | 1 | 2 | 52.6% | 86.7% | 63.0% | 1/2 |
| SF | 103 | Fernando VerdascoClay | 135 | Guillermo CanasClay | 6-3 3-6 6-3 | 3 | 136 | 4 | 5 | 64.5% | 65.3% | 51.9% | 3/7 |
| F | 7 | Carlos MoyaClay | 103 | Fernando VerdascoClay | 6-3 6-0 | 3 | 64 | 3 | 1 | 58.3% | 85.7% | 55.0% | 2/2 |
