| 2012-10-15 | Stockholm | Hard | QF | 7 |  Jo-Wilfried Tsonga (1) | 92 |  Sergiy Stakhovsky | 6-3 6-4 | H2H | 3 | 84 | 7 | 2 | 54.2% | 81.3% | 55.6% | 4/5 |
| 2012-10-15 | Stockholm | Hard | R16 | 92 | Sergiy Stakhovsky | 34 |  Feliciano Lopez (5) | 7-6(5) 7-5 | H2H | 3 | 97 | 16 | 4 | 66.7% | 78.6% | 57.1% | 3/3 |
| 2012-10-15 | Stockholm | Hard | R32 | 92 | Sergiy Stakhovsky | 208 |  Yannick Mertens (Q) | 6-3 6-4 | H2H | 3 | 66 | 7 | 4 | 60.0% | 76.2% | 57.1% | 5/5 |
| 2012-10-01 | Tokyo | Hard | R32 | 46 |  Marcos Baghdatis | 95 | Sergiy Stakhovsky (Q) | 7-6(3) 7-5 | H2H | 3 | 99 | 6 | 4 | 45.1% | 71.9% | 69.2% | 0/1 |
| 2012-09-24 | Bangkok | Hard | R32 | 31 |  Viktor Troicki (6) | 96 | Sergiy Stakhovsky | 6-7(4) 7-5 6-3 | H2H | 3 | 135 | 5 | 2 | 67.3% | 72.1% | 45.5% | 4/8 |
| 2012-09-17 | St. Petersburg | Hard | R16 | 53 |  Fabio Fognini (4) | 95 | Sergiy Stakhovsky | 7-6(4) 6-4 | H2H | 3 | 121 | 0 | 6 | 56.0% | 58.8% | 62.5% | 7/9 |
| 2012-09-17 | St. Petersburg | Hard | R32 | 95 | Sergiy Stakhovsky | 508 |  Ivan Nedelko (LL) | 7-6(2) 6-2 | H2H | 3 | 82 | 5 | 2 | 60.0% | 72.2% | 70.8% | 1/2 |
| 2012-09-14 | Davis Cup G2 R3: LAT vs UKR | Hard | RR | 152 |  Ernests Gulbis | 95 | Sergiy Stakhovsky | 6-0 6-3 6-1 | H2H | 5 | - | - | - | - | - | - | - |
| 2012-09-14 | Davis Cup G2 R3: LAT vs UKR | Hard | RR | 95 | Sergiy Stakhovsky | 376 | Andis Juska | 6-3 6-4 6-4 | H2H | 5 | - | - | - | - | - | - | - |
| 2012-08-27 | US Open | Hard | R128 | 19 |  Stan Wawrinka (18) | 98 | Sergiy Stakhovsky | 6-7(6) 7-6(2) 6-4 6-2 | H2H | 5 | 183 | 12 | 5 | 45.9% | 79.0% | 63.0% | 5/7 |
