| 2010-12-03 | Davis Cup WG F: SRB vs FRA | Hard | RR | 3 |  Novak Djokovic | 42 |  Gilles Simon | 6-3 6-1 7-5 | H2H | 5 | - | - | - | - | - | - | - |
| 2010-12-03 | Davis Cup WG F: SRB vs FRA | Hard | RR | 3 | Novak Djokovic | 12 | Gael Monfils | 6-2 6-2 6-4 | H2H | 5 | - | - | - | - | - | - | - |
| 2010-11-21 | Tour Finals | Hard | SF | 2 |  Roger Federer | 3 | Novak Djokovic | 6-1 6-4 | H2H | 3 | 81 | 4 | 1 | 61.8% | 76.5% | 57.1% | 0/1 |
| 2010-11-21 | Tour Finals | Hard | RR | 3 | Novak Djokovic | 8 |  Andy Roddick | 6-2 6-3 | H2H | 3 | 67 | 6 | 0 | 58.8% | 73.3% | 76.2% | 1/1 |
| 2010-11-21 | Tour Finals | Hard | RR | 3 | Novak Djokovic | 6 |  Tomas Berdych | 6-3 6-3 | H2H | 3 | 88 | 5 | 1 | 61.1% | 78.8% | 61.9% | 0/0 |
| 2010-11-21 | Tour Finals | Hard | RR | 1 |  Rafael Nadal | 3 | Novak Djokovic | 7-5 6-2 | H2H | 3 | 112 | 6 | 0 | 53.2% | 72.7% | 62.1% | 4/5 |
| 2010-11-07 | Paris Masters | Hard | R16 | 34 | Michael Llodra | 3 | Novak Djokovic (2) | 7-6(6) 6-2 | H2H | 3 | 93 | 6 | 4 | 58.6% | 90.2% | 44.8% | 3/3 |
| 2010-11-07 | Paris Masters | Hard | R32 | 3 | Novak Djokovic (2) | 24 |  Juan Monaco | 6-4 6-3 | H2H | 3 | 84 | 8 | 2 | 55.2% | 73.0% | 56.7% | 7/8 |
| 2010-11-01 | Basel | Hard | QF | 3 | Novak Djokovic (2) | 66 |  Robin Haase (Q) | 6-2 6-3 | H2H | 3 | 79 | 5 | 1 | 62.3% | 75.8% | 65.0% | 4/5 |
| 2010-11-01 | Basel | Hard | R32 | 3 | Novak Djokovic (2) | 26 |  Ernests Gulbis | 6-4 6-2 | H2H | 3 | 72 | 5 | 1 | 67.3% | 71.4% | 70.6% | 1/2 |
