| 2020-03-06 | Davis Cup WG1 PO: VEN vs NZL | Hard | RR | - |  Luis David Martinez | 915 |  Ajeet Rai | 5-7 6-4 6-2 | H2H | 3 | 137 | 4 | 1 | 65.1% | 71.4% | 56.7% | 5/8 |
| 2019-09-14 | Davis Cup G1 R1: ECU vs VEN | Hard | RR | 748 |  Cayetano March | 576 | Luis David Martinez | 6-7(3) 7-5 [4-10] | H2H | 3 | - | - | - | - | - | - | - |
| 2019-09-14 | Davis Cup G1 R1: ECU vs VEN | Hard | RR | 249 | Roberto Quiroz | 576 | Luis David Martinez | 6-3 6-3 | H2H | 3 | - | - | - | - | - | - | - |
| 2017-09-15 | Davis Cup G2 R3: BAR vs VEN | Hard | RR | - |  Haydn Lewis | 1095 | Luis David Martinez | 2-6 6-4 6-3 6-4 | H2H | 5 | 199 | 2 | 2 | 80.8% | 68.0% | 47.8% | 12/17 |
| 2017-02-03 | Davis Cup G2 R1: BAH vs VEN | - | RR | 1231 | Luis David Martinez | - |  Spencer Newman | 7-5 6-0 7-6(5) | H2H | 5 | 148 | 2 | 6 | 53.8% | 58.9% | 52.1% | 3/8 |
| 2017-04-07 | Davis Cup G2 R2: ESA vs VEN | Hard | RR | 1210 | Luis David Martinez | - |  Rafael Arevalo | 6-1 6-1 RET | H2H | 5 | - | 0 | 3 | 70.8% | 73.5% | 71.4% | 3/3 |
| 2016-09-16 | Davis Cup G2 R3: PER vs VEN | Clay | RR | - |  Nicolas Alvarez | 740 | Luis David Martinez | 4-6 6-4 7-6(2) 6-1 | H2H | 5 | - | 11 | 4 | 64.9% | 68.0% | 50.0% | 12/14 |
| 2016-03-04 | Davis Cup G2 R1: PAR vs VEN | Hard | RR | 613 | Luis David Martinez | - |  Ayed Zatar | 7-5 3-6 7-6(7) 6-4 | H2H | 5 | 171 | 1 | 7 | 69.9% | 72.6% | 58.5% | 7/10 |
| 2016-07-15 | Davis Cup G2 R2: ESA vs VEN | Hard | RR | 788 | Luis David Martinez | - | Rafael Arevalo | 6-1 7-5 7-5 | H2H | 5 | 131 | 6 | 2 | 57.6% | 73.6% | 61.5% | 3/5 |
| 2015-03-06 | Davis Cup G2 R1: VEN vs CRC | Hard | RR | 640 | Luis David Martinez | - |  Ignaci Roca | 6-3 6-1 | H2H | 3 | - | - | - | - | - | - | - |
