| 2022-10-31 | Paris Masters | Hard | QF | 18 |  Holger Rune | 1 |  Carlos Alcaraz (1) | 6-3 6-6 RET | H2H | 3 | 100 | 5 | 3 | 73.6% | 75.5% | 63.2% | 2/2 |
| 2022-10-31 | Paris Masters | Hard | R16 | 1 | Carlos Alcaraz (1) | 28 |  Grigor Dimitrov | 6-1 6-3 | H2H | 3 | 71 | 1 | 3 | 63.8% | 76.7% | 47.1% | 3/4 |
| 2022-10-31 | Paris Masters | Hard | R32 | 1 | Carlos Alcaraz (1) | 38 |  Yoshihito Nishioka | 6-4 6-4 | H2H | 3 | 72 | 9 | 1 | 73.9% | 85.3% | 66.7% | 0/1 |
| 2022-10-24 | Basel | Hard | SF | 9 |  Felix Auger-Aliassime (3) | 1 | Carlos Alcaraz (1) | 6-3 6-2 | H2H | 3 | 81 | 9 | 0 | 64.7% | 81.8% | 61.1% | 1/1 |
| 2022-10-24 | Basel | Hard | QF | 1 | Carlos Alcaraz (1) | 15 | Pablo Carreno Busta (5) | 6-3 6-4 | H2H | 3 | 99 | 1 | 2 | 67.2% | 76.7% | 47.6% | 4/5 |
| 2022-10-24 | Basel | Hard | R16 | 1 | Carlos Alcaraz (1) | 35 |  Botic van de Zandschulp | 6-4 6-2 | H2H | 3 | 86 | 1 | 1 | 75.0% | 73.3% | 46.7% | 1/2 |
| 2022-10-24 | Basel | Hard | R32 | 1 | Carlos Alcaraz (1) | 45 |  Jack Draper | 3-6 6-2 7-5 | H2H | 3 | 137 | 1 | 2 | 76.9% | 67.1% | 42.9% | 4/7 |
| 2022-10-03 | Astana | Hard | R32 | 66 |  David Goffin (LL) | 1 | Carlos Alcaraz (1) | 7-5 6-3 | H2H | 3 | 106 | 0 | 1 | 53.2% | 72.7% | 48.3% | 7/10 |
| 2022-09-18 | Davis Cup Finals RR: ESP vs KOR | Hard | RR | 1 | Carlos Alcaraz | 74 |  Soonwoo Kwon | 6-4 7-6(1) | H2H | 3 | - | - | - | - | - | - | - |
| 2022-09-16 | Davis Cup Finals RR: ESP vs CAN | Hard | RR | 13 | Felix Auger-Aliassime | 1 | Carlos Alcaraz | 6-7(3) 6-4 6-2 | H2H | 3 | - | - | - | - | - | - | - |
