| 2024-10-28 | Paris Masters | Hard | R16 | 21 |  Karen Khachanov | 24 |  Alexei Popyrin | 7-6(5) 6-4 | H2H | 3 | 116 | 10 | 2 | 75.0% | 74.5% | 64.7% | 3/5 |
| 2024-10-28 | Paris Masters | Hard | R32 | 24 | Alexei Popyrin | 5 | Daniil Medvedev (4) | 6-4 2-6 7-6(4) | H2H | 3 | 150 | 5 | 2 | 66.4% | 70.1% | 41.0% | 9/13 |
| 2024-10-28 | Paris Masters | Hard | R64 | 24 | Alexei Popyrin | 36 |  Matteo Berrettini | 7-5 7-6(2) | H2H | 3 | 116 | 11 | 2 | 61.6% | 79.2% | 54.5% | 5/6 |
| 2024-10-21 | Vienna | Hard | R32 | 51 |  Jakub Mensik (Q) | 25 | Alexei Popyrin (8) | 7-6 6-2 | H2H | 3 | 102 | 5 | 3 | 55.6% | 82.9% | 60.7% | 5/5 |
| 2024-10-02 | Shanghai Masters | Hard | R32 | 10 |  Grigor Dimitrov (9) | 24 | Alexei Popyrin (20) | 7-6(5) 6-2 | H2H | 3 | 88 | 7 | 1 | 64.2% | 97.1% | 68.4% | 0/0 |
| 2024-10-02 | Shanghai Masters | Hard | R64 | 24 | Alexei Popyrin (20) | 55 |  Miomir Kecmanovic | 6-3 6-2 | H2H | 3 | 61 | 13 | 2 | 69.8% | 86.5% | 37.5% | 4/4 |
| 2024-09-25 | Tokyo | Hard | R32 | 34 | Tomas Machac | 23 | Alexei Popyrin | 6-3 6-7(5) 7-5 | H2H | 3 | 149 | 10 | 1 | 70.3% | 84.5% | 60.0% | 4/4 |
| 2024-09-10 | Davis Cup Finals RR: AUS vs FRA | Hard | RR | 18 |  Ugo Humbert | 24 | Alexei Popyrin | 6-3 6-2 | H2H | 3 | 71 | 5 | 1 | 68.6% | 80.0% | 50.0% | 3/4 |
| 2024-09-12 | Davis Cup Finals RR: AUS vs CZE | Hard | RR | 24 | Alexei Popyrin | 35 | Tomas Machac | 1-0 RET | H2H | 3 | 6 | 1 | 0 | 66.7% | 75.0% | 50.0% | 0/0 |
| 2024-09-15 | Davis Cup Finals RR: AUS vs ESP | Hard | RR | 24 | Alexei Popyrin | 42 |  Pedro Martinez | 6-4 6-4 | H2H | 3 | 89 | 9 | 2 | 64.2% | 76.7% | 54.2% | 3/3 |
