| 2026-04-18 | Munich | Clay | SF | 6 |  Ben Shelton (2) | 166 |  Alex Molcan | 6-3 6-4 | H2H | 3 | 96 | 6 | 2 | 59.7% | 73.0% | 68.0% | 1/1 |
| 2026-04-17 | Munich | Clay | QF | 166 | Alex Molcan | 39 |  Denis Shapovalov | 6-4 6-4 | H2H | 3 | 78 | 2 | 3 | 53.8% | 67.9% | 79.2% | 0/1 |
| 2026-04-16 | Munich | Clay | R16 | 166 | Alex Molcan | 56 |  Daniel Altmaier | 6-4 7-6(10) | H2H | 3 | 103 | 2 | 0 | 63.2% | 83.7% | 64.0% | 0/0 |
| 2026-04-14 | Munich | Clay | R32 | 166 | Alex Molcan | 11 |  Alexander Bublik (3) | 6-4 6-2 | H2H | 3 | 65 | 6 | 1 | 60.8% | 74.2% | 60.0% | 1/2 |
| 2026-04-03 | Bucharest | Clay | QF | 60 |  Mariano Navone (7) | 189 | Alex Molcan | 3-6 6-2 6-3 | H2H | 3 | 138 | 1 | 0 | 73.4% | 63.8% | 47.6% | 4/8 |
| 2026-04-01 | Bucharest | Clay | R16 | 189 | Alex Molcan | 36 | Gabriel Diallo (1) | 6-2 6-2 | H2H | 3 | 87 | 2 | 4 | 54.5% | 83.3% | 40.0% | 6/7 |
| 2026-04-01 | Bucharest | Clay | R32 | 189 | Alex Molcan | 107 |  Matteo Arnaldi | 6-3 6-1 | H2H | 3 | 72 | 6 | 1 | 71.4% | 80.0% | 58.3% | 2/3 |
| 2026-02-06 | Davis Cup QLS R1: FRA vs SVK | Hard | RR | 31 |  Arthur Rinderknech | 200 | Alex Molcan | 7-5 7-6(6) | H2H | 3 | 118 | 16 | 1 | 78.5% | 79.0% | 47.1% | 5/6 |
| 2026-02-06 | Davis Cup QLS R1: FRA vs SVK | Hard | RR | 200 | Alex Molcan | 49 | Alexandre Muller | 6-4 6-4 | H2H | 3 | 46 | 4 | 0 | 75.4% | 72.1% | 85.7% | 2/3 |
| 2025-09-12 | Davis Cup WG1 R1: SVK vs COL | Hard | RR | 201 | Alex Molcan | 200 |  Nicolas Mejia | 6-4 7-6(4) | H2H | 3 | 146 | 0 | 1 | 69.7% | 67.4% | 65.0% | 2/5 |
