| 2022-11-22 | Davis Cup Finals QF: AUS vs NED | Hard | RR | 24 |  Alex de Minaur | 35 |  Botic van de Zandschulp | 5-7 6-3 6-4 | H2H | 3 | - | - | - | - | - | - | - |
| 2022-11-27 | Davis Cup Finals F: CAN vs AUS | Hard | RR | 6 |  Felix Auger-Aliassime | 24 | Alex de Minaur | 6-3 6-4 | H2H | 3 | - | - | - | - | - | - | - |
| 2022-11-25 | Davis Cup Finals SF: AUS vs CRO | Hard | RR | 24 | Alex de Minaur | 17 |  Marin Cilic | 6-2 6-2 | H2H | 3 | - | - | - | - | - | - | - |
| 2022-10-31 | Paris Masters | Hard | R16 | 21 |  Frances Tiafoe (16) | 25 | Alex de Minaur | 6-3 7-6(5) | H2H | 3 | 100 | 14 | 3 | 58.4% | 73.3% | 53.1% | 4/5 |
| 2022-10-31 | Paris Masters | Hard | R32 | 25 | Alex de Minaur | 3 |  Daniil Medvedev (4) | 6-4 2-6 7-5 | H2H | 3 | 166 | 1 | 1 | 59.0% | 67.7% | 51.2% | 12/15 |
| 2022-10-31 | Paris Masters | Hard | R64 | 25 | Alex de Minaur | 33 | Sebastian Korda | 6-4 4-6 6-4 | H2H | 3 | 162 | 2 | 4 | 65.4% | 69.1% | 47.2% | 11/13 |
| 2022-10-24 | Basel | Hard | R32 | 25 |  Holger Rune | 24 | Alex de Minaur (7) | 6-2 7-5 | H2H | 3 | 89 | 8 | 2 | 69.2% | 77.8% | 50.0% | 3/3 |
| 2022-10-17 | Stockholm | Hard | QF | 23 | Alex de Minaur (5) | 20 | Denis Shapovalov (4) | 6-2 7-6(4) | H2H | 3 | 99 | 0 | 1 | 65.7% | 79.5% | 56.5% | 3/4 |
| 2022-10-17 | Stockholm | Hard | R16 | 23 | Alex de Minaur (5) | 56 | J.J. Wolf | 6-4 6-2 | H2H | 3 | 83 | 4 | 0 | 67.8% | 70.0% | 57.9% | 4/5 |
| 2022-10-17 | Stockholm | Hard | R32 | 23 | Alex de Minaur (5) | 63 |  Benjamin Bonzi | 6-3 6-1 | H2H | 3 | 76 | 2 | 1 | 60.9% | 82.1% | 61.1% | 0/0 |
