| 2022-03-04 | Davis Cup QLS R1: USA vs COL | Hard | RR | 20 |  Taylor Fritz | 453 |  Alejandro Gonzalez | 6-1 6-0 | H2H | 3 | 53 | 5 | 2 | 53.7% | 86.4% | 52.6% | 0/0 |
| 2019-11-19 | Davis Cup Finals RR: AUS vs COL | Hard | RR | 30 |  Nick Kyrgios | 470 | Alejandro Gonzalez | 6-4 6-4 | H2H | 3 | 71 | 16 | 1 | 78.3% | 88.9% | 80.0% | 0/0 |
| 2019-02-01 | Davis Cup QLS R1: SWE vs COL | Clay | RR | 337 | Alejandro Gonzalez | 116 |  Elias Ymer | 6-3 6-3 | H2H | 3 | 56 | 1 | 3 | 61.8% | 64.7% | 66.7% | 2/4 |
| 2018-02-02 | Davis Cup G1 R1: COL vs BAR | Hard | RR | 328 | Alejandro Gonzalez | 169 |  Darian King | 7-5 6-3 | H2H | 3 | 96 | 3 | 2 | 66.7% | 65.9% | 50.0% | 4/7 |
| 2018-04-06 | Davis Cup G1 R2: COL vs BRA | Hard | RR | 305 | Alejandro Gonzalez | 359 |  Joao Pedro Sorgi | 6-3 7-6(0) | H2H | 3 | 85 | 2 | 0 | 64.7% | 75.8% | 55.6% | 2/3 |
| 2017-09-15 | Davis Cup WG PO: CRO vs COL | Clay | RR | 239 |  Viktor Galovic | 484 | Alejandro Gonzalez | 6-4 2-6 6-2 | H2H | 3 | 82 | 7 | 5 | 57.8% | 81.1% | 51.9% | 2/6 |
| 2017-09-15 | Davis Cup WG PO: CRO vs COL | Clay | RR | 5 | Marin Cilic | 484 | Alejandro Gonzalez | 6-1 6-4 6-1 | H2H | 5 | 111 | 13 | 2 | 55.2% | 83.8% | 66.7% | 1/1 |
| 2016-09-16 | Davis Cup G1 R2: COL vs DOM | Clay | RR | 164 | Alejandro Gonzalez | - |  Roberto Cid Subervi | 6-2 2-6 6-3 | H2H | 3 | - | - | - | - | - | - | - |
| 2016-09-16 | Davis Cup G1 R2: COL vs DOM | Clay | RR | 77 | Victor Estrella Burgos | 164 | Alejandro Gonzalez | 6-4 1-6 6-3 6-4 | H2H | 5 | - | - | - | - | - | - | - |
| 2016-07-25 | Canada Masters | Hard | R64 | 22 | Bernard Tomic (12) | 163 | Alejandro Gonzalez (Q) | 6-4 7-6(1) | H2H | 3 | 90 | 7 | 3 | 58.1% | 75.0% | 42.3% | 0/3 |
